Electronicvs. Steric Hindrance Effects in Amine Ligands to Ru-Based Initiators for ROMP
نویسندگان
چکیده
منابع مشابه
Steric hindrance effects in thin reaction zones: applications to BIAcore
Many biological and industrial processes have reactions which occur in thin zones of densely packed receptors. Understanding the rate of such reactions is important, and the BIAcore surface plasmon resonance biosensor for measuring rate constants has such a geometry. However, interpreting biosensor data correctly is difficult since large ligand molecules can block multiple receptor sites, thus ...
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Because surface-volume reactions occur in many biological and industrial processes, understanding the rate of such reactions is important. The BIAcore surface plasmon resonance (SPR) biosensor for measuring rate constants has such a geometry. Though several models of the BIAcore have been presented, few take into account that large ligand molecules can block multiple receptor sites, thus skewin...
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A straightforward synthesis utilizing the ring-opening metathesis polymerization (ROMP) reaction is described for acid-triggered N,O-chelating ruthenium-based pre-catalysts bearing one or two 8-quinolinolate ligands. The innovative pre-catalysts were tested regarding their behavior in ROMP and especially for their use in the synthesis of poly(dicyclopentadiene) (pDCPD). Bearing either the commo...
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Correction for 'Electrochromic sensing platform based on steric hindrance effects for CEA detection' by Qingfeng Zhai et al., Analyst, 2016, DOI: 10.1039/c6an00675b.
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In this work, an electrochromic sensing platform with prussian blue (PB) as the indicator was proposed for signaling carcinoembryonic antigen (CEA) using the bipolar electrode (BPE) system. The CEA aptamer was pre-anchored on the anode pole of the BPE for capturing CEA through strong binding affinity. The presence of CEA induced the increase of steric hindrance and led to lower electrochemical ...
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ژورنال
عنوان ژورنال: Journal of the Brazilian Chemical Society
سال: 2014
ISSN: 0103-5053
DOI: 10.5935/0103-5053.20140269